| Literature DB >> 28317199 |
Tian-Chen Kang1, Lu-Ping Wu1, Qi-Wen Yu1, Xin-Yan Wu1.
Abstract
An unprecedented Rauhut-Currier-type 1,6-conjugate addition has been developed. With chiral cyclohexane-based phosphine-amide catalyst 3 h, the 1,6-conjugate reaction has been achieved to produce chiral diarylmethine compounds in excellent yields (91-99 %) and enantioselectivities (92-98 % ee).Entities:
Keywords: asymmetric catalysis; chiral phosphine; conjugation; quinone methide; rauhut-currier
Year: 2017 PMID： 28317199 DOI： 10.1002/chem.201700520
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236