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Literature DB >> 28294489

Iterative C-H Functionalization Leading to Multiple Amidations of Anilides.

Juhyeon Park^1,2, Jia Lee^1,2, Sukbok Chang^1,2.

Abstract

Polyaminobenzenes were synthesized by the ruthenium-catalyzed iterative C-H amidation of anilides using dioxazolones as an amino source. This strategy could be implemented by the sequential activation of C-H bonds of formerly generated compounds by cascade chelation assistance of newly installed amide groups. Computational studies provided a rationale.

Entities: Chemical

Keywords: C−H activation; amidation; arenes; reaction mechanisms; ruthenium

Year: 2017 PMID： 28294489 DOI： 10.1002/anie.201701138

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

5 in total

1. Rhodium^III-catalyzed remote difunctionalization of arenes assisted by a relay directing group.

Authors: Lincong Sun; Yuyao Zhao; Bingxian Liu; Junbiao Chang; Xingwei Li
Journal: Chem Sci Date: 2022-05-30 Impact factor: 9.969

Review 2. A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors: Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal: Chem Soc Rev Date: 2018-08-28 Impact factor: 54.564

Iterative C-H Functionalization Leading to Multiple Amidations of Anilides.

1. Rhodium^III-catalyzed remote difunctionalization of arenes assisted by a relay directing group.

Review 2. A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

3. Anti-Food Allergic Compounds from Penicillium griseofulvum MCCC 3A00225, a Deep-Sea-Derived Fungus.

4. Design and Synthesis of 6-O-Phosphorylated Heparan Sulfate Oligosaccharides to Inhibit Amyloid β Aggregation.

5. Thiocarbonyl-enabled ferrocene C-H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical.

Iterative C-H Functionalization Leading to Multiple Amidations of Anilides.

1. RhodiumIII-catalyzed remote difunctionalization of arenes assisted by a relay directing group.

Review 2. A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

3. Anti-Food Allergic Compounds from Penicillium griseofulvum MCCC 3A00225, a Deep-Sea-Derived Fungus.

4. Design and Synthesis of 6-O-Phosphorylated Heparan Sulfate Oligosaccharides to Inhibit Amyloid β Aggregation.

5. Thiocarbonyl-enabled ferrocene C-H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical.

1. Rhodium^III-catalyzed remote difunctionalization of arenes assisted by a relay directing group.