| Literature DB >> 28287236 |
Lander Verstraete1, Brandon E Hirsch, John Greenwood, Steven De Feyter.
Abstract
Polydiacetylene polymers of defined lengths are formed from self-assembled precursors inside nanocorrals created within grafted graphite substrates. A scanning tunneling microscope tip is used to nanoshave corrals at the liquid-solid interface allowing orientationally controlled supramolecular self-assembly of linear diacetylene molecules. Electrical pulses trigger topological one-dimensional polymerization reactions that are confined by the nanocorral template dimensions.Entities:
Year: 2017 PMID： 28287236 DOI： 10.1039/c7cc00885f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222