| Literature DB >> 28256071 |
Yong-Yuan Gui1, Wen-Jun Zhou1,2, Jian-Heng Ye1, Da-Gang Yu1.
Abstract
From ugly duckling to beautiful C1: Although CO2 may represent an ideal C1 source, it is challenging to use it as a raw material and direct carboxylation with CO2 has mainly been confined to highly reactive species. However, recent significant breakthroughs have been made in photochemical carboxylation of challenging, un-acidic, C(sp3 )-H bonds, including benzylic, allylic and amine C-H bonds.Entities:
Keywords: C1 building blocks; C−H activation; carbon dioxide; carboxylation; photochemistry
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Year: 2017 PMID： 28256071 DOI： 10.1002/cssc.201700205
Source DB: PubMed Journal: ChemSusChem ISSN： 1864-5631 Impact factor: 8.928