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Literature DB >> 28218478

Exceptionally High Ionic Conductivity in Na₃ P_0.62 As_0.38 S₄ with Improved Moisture Stability for Solid-State Sodium-Ion Batteries.

Zhaoxin Yu¹, Shun-Li Shang², Joo-Hwan Seo², Daiwei Wang¹, Xiangyi Luo³, Qingquan Huang², Shuru Chen¹, Jun Lu³, Xiaolin Li⁴, Zi-Kui Liu², Donghai Wang¹.

Abstract

A Na-ion solid-state electrolyte, Na3 P0.62 As0.38 S4 , is developed with an exceptionally high conductivity of 1.46 mS cm-1 at 25 °C and enhanced moisture stability. Dual effects of alloying element As (lattice expansion and a weaker AsS bond strength) are responsible for the superior conductivity. Improved moisture stability is regulated by shifting low-energy moisture reactions to high-energy ones due to As.

Entities: Chemical

Keywords: all-solid-state battery; first-principles calculations; sodium-ion conductor; solid-state electrolyte; sulfide

Year: 2017 PMID： 28218478 DOI： 10.1002/adma.201605561

Source DB: PubMed Journal: Adv Mater ISSN： 0935-9648 Impact factor: 30.849

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Cited

6 in total

1. Evidence for a Solid-Electrolyte Inductive Effect in the Superionic Conductor Li₁₀Ge_1-xSn_xP₂S₁₂.

Authors: Sean P Culver; Alexander G Squires; Nicolò Minafra; Callum W F Armstrong; Thorben Krauskopf; Felix Böcher; Cheng Li; Benjamin J Morgan; Wolfgang G Zeier
Journal: J Am Chem Soc Date: 2020-12-07 Impact factor: 15.419

Review 2. Building Better Batteries in the Solid State: A Review.

Authors: Alain Mauger; Christian M Julien; Andrea Paolella; Michel Armand; Karim Zaghib
Journal: Materials (Basel) Date: 2019-11-25 Impact factor: 3.623

3. An electrochemically stable homogeneous glassy electrolyte formed at room temperature for all-solid-state sodium batteries.

Authors: Xiaowei Chi; Ye Zhang; Fang Hao; Steven Kmiec; Hui Dong; Rong Xu; Kejie Zhao; Qing Ai; Tanguy Terlier; Liang Wang; Lihong Zhao; Liqun Guo; Jun Lou; Huolin L Xin; Steve W Martin; Yan Yao
Journal: Nat Commun Date: 2022-05-23 Impact factor: 17.694

Exceptionally High Ionic Conductivity in Na₃ P_0.62 As_0.38 S₄ with Improved Moisture Stability for Solid-State Sodium-Ion Batteries.

1. Evidence for a Solid-Electrolyte Inductive Effect in the Superionic Conductor Li₁₀Ge_1-xSn_xP₂S₁₂.

Review 2. Building Better Batteries in the Solid State: A Review.

3. An electrochemically stable homogeneous glassy electrolyte formed at room temperature for all-solid-state sodium batteries.

4. Preparation of cubic Na₃PS₄ by liquid-phase shaking in methyl acetate medium.

5. Novel Solid-State Sodium-Ion Battery with Wide Band Gap NaTi₂(PO₄)₃ Nanocrystal Electrolyte.

Review 6. Na ion batteries: An India centric review.

Exceptionally High Ionic Conductivity in Na3 P0.62 As0.38 S4 with Improved Moisture Stability for Solid-State Sodium-Ion Batteries.

1. Evidence for a Solid-Electrolyte Inductive Effect in the Superionic Conductor Li10Ge1-xSnxP2S12.

Review 2. Building Better Batteries in the Solid State: A Review.

3. An electrochemically stable homogeneous glassy electrolyte formed at room temperature for all-solid-state sodium batteries.

4. Preparation of cubic Na3PS4 by liquid-phase shaking in methyl acetate medium.

5. Novel Solid-State Sodium-Ion Battery with Wide Band Gap NaTi2(PO4)3 Nanocrystal Electrolyte.

Review 6. Na ion batteries: An India centric review.

Exceptionally High Ionic Conductivity in Na₃ P_0.62 As_0.38 S₄ with Improved Moisture Stability for Solid-State Sodium-Ion Batteries.

1. Evidence for a Solid-Electrolyte Inductive Effect in the Superionic Conductor Li₁₀Ge_1-xSn_xP₂S₁₂.

4. Preparation of cubic Na₃PS₄ by liquid-phase shaking in methyl acetate medium.

5. Novel Solid-State Sodium-Ion Battery with Wide Band Gap NaTi₂(PO₄)₃ Nanocrystal Electrolyte.