| Literature DB >> 28214428 |
Sofya B Artemkina1, Ekaterina D Grayfer2, Mariia N Kozlova2, Svetlana G Kozlova3, Maxim R Ryzhikov1, Igor R Shein4, Vladimir E Fedorov1.
Abstract
For the first time the comparison of the theoretical and experimental data have shown that UV-vis absorption in the region of 600nm in colloidal solution of NbS3 can be described by the d-d electronic transitions to the antibonding molecular orbital. It is proved that the process leads to excitation of metal-metal bond.Entities:
Keywords: Band calculations; DFT; NbS(3) colloidal dispersion; UV–vis spectra
Year: 2017 PMID： 28214428 DOI： 10.1016/j.saa.2017.02.005
Source DB: PubMed Journal: Spectrochim Acta A Mol Biomol Spectrosc ISSN： 1386-1425 Impact factor: 4.098