Vinícius Esteves Salgado1, Larissa Maria Cavalcante2, Rafael R Moraes3, Harry B Davis4, Jack L Ferracane4, Luis Felipe Schneider5. 1. Graduate Program in Dentistry, Federal University of Pelotas, Pelotas, RS, Brazil; School of Dentistry, Salgado de Oliveira University, Niterói, RJ, Brazil. Electronic address: salgadouff@gmail.com. 2. School of Dentistry, Salgado de Oliveira University, Niterói, RJ, Brazil; School of Dentistry, Federal Fluminense University, Niterói, RJ, Brazil. 3. Graduate Program in Dentistry, Federal University of Pelotas, Pelotas, RS, Brazil. 4. Division of Biomaterials & Biomechanics, Oregon Health & Science University, Portland, OR, USA. 5. School of Dentistry, Federal Fluminense University, Niterói, RJ, Brazil; Nucleus for Dental Biomaterials Research, Veiga de Almeida University, Rio de Janeiro, RJ, Brazil.
Abstract
OBJECTIVE: To determine the optical and surface properties of model resin-based composites made with distinct nanoparticle sizes but equalized surface area, among them, before and after ageing. METHODS: Model resin-based composites based on BisGMA/TEGDMA (50:50mol%) were loaded with three different fumed silica filler content (7nm/examethyldisilazane, 12nm/octylsilane, and 16nm/dimethylchlorosilane), but with equivalent surface area (BET method). The optical and surface properties of the disk-shaped specimens were measured in 24h after photoactivation (baseline) and repeated after water storage (90days at 37°C), and after abrasion (20,000 cycles of brushing). CIELAB individual parameters, color difference (ΔE*ab), translucency parameter (TP), gloss (G.U.) and roughness (Ra parameter) were measured. Data were statistically analyzed at α=0.05 significance level. RESULTS: CIE L* and TP were not affected by ageing in any group. CIE a* was increased and CIE b* decreased for the 12nm and 16nm groups and did not show any difference for the 7nm group. After ageing, the lowest ΔE*ab was observed for the 7nm group. Gloss and roughness were statistically equivalent for all groups, before and after ageing. The water storage didn't show any significant difference while the abrasion decreased gloss and increased the roughness. CONCLUSION: The optical properties of the tested materials were not dependent of the fillers' surface area, while the surface properties were. CLINICAL SIGNIFICANCE: Several factors influence the ageing resistance of the resin-based composites, including the surface area of the fillers and the amount and coupling treatment of them. The improvement of the material's physical stability could avoid the premature replacement of dental restorations.
OBJECTIVE: To determine the optical and surface properties of model resin-based composites made with distinct nanoparticle sizes but equalized surface area, among them, before and after ageing. METHODS: Model resin-based composites based on BisGMA/TEGDMA (50:50mol%) were loaded with three different fumed silica filler content (7nm/examethyldisilazane, 12nm/octylsilane, and 16nm/dimethylchlorosilane), but with equivalent surface area (BET method). The optical and surface properties of the disk-shaped specimens were measured in 24h after photoactivation (baseline) and repeated after water storage (90days at 37°C), and after abrasion (20,000 cycles of brushing). CIELAB individual parameters, color difference (ΔE*ab), translucency parameter (TP), gloss (G.U.) and roughness (Ra parameter) were measured. Data were statistically analyzed at α=0.05 significance level. RESULTS: CIE L* and TP were not affected by ageing in any group. CIE a* was increased and CIE b* decreased for the 12nm and 16nm groups and did not show any difference for the 7nm group. After ageing, the lowest ΔE*ab was observed for the 7nm group. Gloss and roughness were statistically equivalent for all groups, before and after ageing. The water storage didn't show any significant difference while the abrasion decreased gloss and increased the roughness. CONCLUSION: The optical properties of the tested materials were not dependent of the fillers' surface area, while the surface properties were. CLINICAL SIGNIFICANCE: Several factors influence the ageing resistance of the resin-based composites, including the surface area of the fillers and the amount and coupling treatment of them. The improvement of the material's physical stability could avoid the premature replacement of dental restorations.