Literature DB >> 28210727

Mn(iv) and Mn(v)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand.

Nicolas Leconte1, Jules Moutet1, Khrystyna Herasymchuk2, Ryan M Clarke2, Christian Philouze1, Dominique Luneau3, Tim Storr2, Fabrice Thomas1.   

Abstract

The electron-rich pincer ligand 1 has been synthesized and chelated to manganese. The octahedral Mn(iv) bis(diiminosemiquinonate) and Mn(v) (diiminobenzoquinone) (diiminosemiquinonate) radicals were structurally characterized.

Entities:  

Year:  2017        PMID： 28210727     DOI： 10.1039/c7cc00516d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity.

Authors:  Sarah A Cook; Justin A Bogart; Noam Levi; Andrew C Weitz; Curtis Moore; Arnold L Rheingold; Joseph W Ziller; Michael P Hendrich; A S Borovik
Journal:  Chem Sci       Date:  2018-07-02       Impact factor: 9.825

2.  Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.

Authors:  Jarl Ivar van der Vlugt
Journal:  Chemistry       Date:  2018-11-26       Impact factor: 5.236
  2 in total

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