Literature DB >> 28205443

A Stereoselective Arylative-Cyclopropanation Process.

Siomenan Coulibali1, Elsa Deruer1, Elizabeth Godin1, Sylvain Canesi1.   

Abstract

A new stereoselective arylative cyclopropanation process involving treatment of halogenated dienone systems in the presence of a Michael donor containing a nitro-aryl-sulfone has been developed. This transformation enables production of an arylated cyclopropane under mild conditions and occurs via a Michael-Smiles ring closure cascade process, reflecting the concepts of green chemistry and atom economy.

Entities:  

Year:  2017        PMID: 28205443     DOI: 10.1021/acs.orglett.7b00248

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Rapid transformation of sulfinate salts into sulfonates promoted by a hypervalent iodine(III) reagent.

Authors:  Elsa Deruer; Vincent Hamel; Samuel Blais; Sylvain Canesi
Journal:  Beilstein J Org Chem       Date:  2018-05-24       Impact factor: 2.883

  1 in total

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