Photodegradation of diclofenac in seawater by simulated sunlight irradiation: The comprehensive effect of nitrate, Fe(III) and chloride.

Diclofenac is one of the most frequently detected pharmaceuticals in various aquatic environments. The photodegradation of diclofenac in the absence/presence of nitrate, Fe(III) and chloride, especially their interactions, were systematically studied. Under the study conditions, photodegradation rate was decreased with increasing nitrate, Fe(III) and chloride concentrations. Nitrate has an synergistic action for Fe(III). Nitrate and chloride have antagonistic effect. An antagonistic action is present between nitrate, Fe(III) and chloride. Moreover, a simple linear model which very well describes the results is given.