Literature DB >> 28195386

A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus.

Douglas W Stephan1.   

Abstract

This Minireview focuses on the Lewis acidity/basicity "umpolung" of boron-based nucleophiles and phosphorus-based electrophiles.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Lewis acidity/basicity umpolung; boron nucleophiles; catalysis; electrophilic phosphonium cations; phosphorus Lewis acids

Year:  2017        PMID： 28195386     DOI： 10.1002/anie.201700721

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Tuning the electrochemical potential of perfunctionalized dodecaborate clusters through vertex differentiation.

Authors:  Alex I Wixtrom; Zeeshan A Parvez; Miles D Savage; Elaine A Qian; Dahee Jung; Saeed I Khan; Arnold L Rheingold; Alexander M Spokoyny
Journal:  Chem Commun (Camb)       Date:  2018-06-05       Impact factor: 6.222

2.  A crystalline radical cation derived from Thiele's hydrocarbon with redox range beyond 1 V.

Authors:  Ying Kai Loh; Petra Vasko; Caitilín McManus; Andreas Heilmann; William K Myers; Simon Aldridge
Journal:  Nat Commun       Date:  2021-12-03       Impact factor: 14.919

3.  Synthesis and Structure of Mono-, Di-, and Trinuclear Fluorotriarylbismuthonium Cations.

Authors:  Jennifer Kuziola; Marc Magre; Nils Nöthling; Josep Cornella
Journal:  Organometallics       Date:  2022-05-09       Impact factor: 3.837

4.  Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC-B(CN)2.

Authors:  Richard Böser; Lisa C Haufe; Matthias Freytag; Peter G Jones; Gerald Hörner; René Frank
Journal:  Chem Sci       Date:  2017-07-03       Impact factor: 9.825
  4 in total

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