Literature DB >> 28194848

A General and Highly Selective Cobalt-Catalyzed Hydrogenation of N-Heteroarenes under Mild Reaction Conditions.

Rosa Adam1, Jose R Cabrero-Antonino1, Anke Spannenberg1, Kathrin Junge1, Ralf Jackstell1, Matthias Beller1.   

Abstract

Herein, a general and efficient method for the homogeneous cobalt-catalyzed hydrogenation of N-heterocycles, under mild reaction conditions, is reported. Key to success is the use of the tetradentate ligand tris(2-(diphenylphosphino)phenyl)phosphine). This non-noble metal catalyst system allows the selective hydrogenation of heteroarenes in the presence of a broad range of other sensitive reducible groups.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  cobalt; homogeneous catalysis; hydrogenation; nitrogen heterocycles; phosphines

Year:  2017        PMID： 28194848     DOI： 10.1002/anie.201612290

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

1.  A new route to N-aromatic heterocycles from the hydrogenation of diesters in the presence of anilines.

Authors:  Yiping Shi; Paul C J Kamer; David J Cole-Hamilton; Michelle Harvie; Emma F Baxter; Kate J C Lim; Peter Pogorzelec
Journal:  Chem Sci       Date:  2017-08-08       Impact factor: 9.825

2.  A robust iron catalyst for the selective hydrogenation of substituted (iso)quinolones.

Authors:  Basudev Sahoo; Carsten Kreyenschulte; Giovanni Agostini; Henrik Lund; Stephan Bachmann; Michelangelo Scalone; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2018-09-06       Impact factor: 9.825

3.  Interrupted Pyridine Hydrogenation: Asymmetric Synthesis of δ-Lactams.

Authors:  Tobias Wagener; Lukas Lückemeier; Constantin G Daniliuc; Frank Glorius
Journal:  Angew Chem Int Ed Engl       Date:  2021-02-12       Impact factor: 15.336

4.  Iridium Complex-Catalyzed Transfer Hydrogenation of N-Heteroarenes and Tentative Asymmetric Synthesis.

Authors:  Lu Ouyang; Yanping Xia; Jianhua Liao; Rui Miao; Xiao Yang; Renshi Luo
Journal:  ACS Omega       Date:  2021-04-07

5.  Ligand-enabled and magnesium-activated hydrogenation with earth-abundant cobalt catalysts.

Authors:  Bo Han; Miaomiao Zhang; Hongmei Jiao; Haojie Ma; Jijiang Wang; Yuqi Zhang
Journal:  RSC Adv       Date:  2021-12-15       Impact factor: 4.036

6.  Cobalt-catalysed reductive C-H alkylation of indoles using carboxylic acids and molecular hydrogen.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-07-26       Impact factor: 9.825

7.  Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Mattes Holsten; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-06-12       Impact factor: 9.825

Review 8.  Selective Arene Hydrogenation for Direct Access to Saturated Carbo- and Heterocycles.

Authors:  Mario P Wiesenfeldt; Zackaria Nairoukh; Toryn Dalton; Frank Glorius
Journal:  Angew Chem Int Ed Engl       Date:  2019-04-29       Impact factor: 15.336

9.  Synthesis of Tetrahydroquinolines via Borrowing Hydrogen Methodology Using a Manganese PN3 Pincer Catalyst.

Authors:  Natalie Hofmann; Leonard Homberg; Kai C Hultzsch
Journal:  Org Lett       Date:  2020-09-24       Impact factor: 6.005

10.  A General Catalyst Based on Cobalt Core-Shell Nanoparticles for the Hydrogenation of N-Heteroarenes Including Pyridines.

Authors:  Kathiravan Murugesan; Vishwas G Chandrashekhar; Carsten Kreyenschulte; Matthias Beller; Rajenahally V Jagadeesh
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-17       Impact factor: 16.823
  10 in total

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