Engineering of Ruthenium(II) Photosensitizers with Non-Innocent Oxyquinolate and Carboxyamidoquinolate Ligands for Dye-Sensitized Solar Cells.

An alternative approach to replacing the isothiocyantate ligands of the N3 photosensitizer with light-harvesting bidentate ligands is investigated for application in dye-sensitized solar cells (DSSCs). An in-depth theoretical analysis has been applied to investigate the optical and redox properties of four non-innocent ligand platforms, which is then corroborated with experiment. Taking advantage of the 5- and 7-positions of 8-oxyquinolate, or the carboxyaryl ring system of the N-arylcarboxy-8-amidoquinolate ligand, fluorinated aryl substituents are demonstrated as an effective means of tuning complex redox potentials and light-harvesting properties. The non-innocent character, resulting from mixing of both the central metal-dπ and ligand-π manifolds, generates hybrid metal-ligand frontier orbitals. These play a major role by contributing to the redox properties and visible electronic transitions, and promoting an improved power conversion efficiency in a Ru DSSC device featuring non-innocent ligands.