Literature DB >> 28185372

Ni-Catalyzed Stannylation of Aryl Esters via C-O Bond Cleavage.

Yiting Gu1, Rúben Martín1,2.   

Abstract

A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents via Csp2 -O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C-heteroatom bond formations.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−O cleavage; aryl esters; cross-coupling; nickel

Year:  2017        PMID： 28185372     DOI： 10.1002/anie.201611720

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Mechanism and Origins of Ligand-Controlled Stereoselectivity of Ni-Catalyzed Suzuki-Miyaura Coupling with Benzylic Esters: A Computational Study.

Authors:  Shuo-Qing Zhang; Buck L H Taylor; Chong-Lei Ji; Yuan Gao; Michael R Harris; Luke E Hanna; Elizabeth R Jarvo; K N Houk; Xin Hong
Journal:  J Am Chem Soc       Date:  2017-09-07       Impact factor: 15.419

2.  Transesterification of (hetero)aryl esters with phenols by an Earth-abundant metal catalyst.

Authors:  Jianxia Chen; E Namila; Chaolumen Bai; Menghe Baiyin; Bao Agula; Yong-Sheng Bao
Journal:  RSC Adv       Date:  2018-07-13       Impact factor: 4.036

3.  Addition of arylstannanes to alkynes giving ortho-alkenylarylstannanes catalysed cooperatively by a rhodium complex and zinc chloride.

Authors:  Jialin Ming; Qi Shi; Tamio Hayashi
Journal:  Chem Sci       Date:  2018-08-17       Impact factor: 9.825

4.  Heterogeneous Suzuki-Miyaura coupling of heteroaryl ester via chemoselective C(acyl)-O bond activation.

Authors:  Hongpeng Ma; Chaolumen Bai; Yong-Sheng Bao
Journal:  RSC Adv       Date:  2019-06-03       Impact factor: 4.036
  4 in total

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