Literature DB >> 28154846

Second sphere ligand modifications enable a recyclable catalyst for oxidant-free alcohol oxidation to carboxylates.

Eric W Dahl1, Thomas Louis-Goff1, Nathaniel K Szymczak1.   

Abstract

Modification of the classic terpyridine pincer ligand with pendent NHR (R = mesityl) groups provides enhanced activity and stability in Ru-catalyzed dehydrogenation catalysis. These second sphere modifications furnish highly active catalysts for the oxidant-free dehydrogenative oxidation of primary alcohols to carboxylates and facilitate catalyst recycling.

Entities:  

Year:  2017        PMID： 28154846     DOI： 10.1039/c6cc10206a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Terpyridine-metal complexes: Applications in catalysis and supramolecular chemistry.

Authors:  Chiyu Wei; Ying He; Xiaodong Shi; Zhiguang Song
Journal:  Coord Chem Rev       Date:  2019-01-28       Impact factor: 22.315

2.  Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes.

Authors:  E W Dahl; H T Dong; N K Szymczak
Journal:  Chem Commun (Camb)       Date:  2018-01-23       Impact factor: 6.222

3.  Hydrogen-bonded nickel(I) complexes.

Authors:  Jessica R Wilson; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Commun (Camb)       Date:  2021-01-26       Impact factor: 6.222

4.  Incorporation of redox-inactive cations promotes iron catalyzed aerobic C-H oxidation at mild potentials.

Authors:  Teera Chantarojsiri; Joseph W Ziller; Jenny Y Yang
Journal:  Chem Sci       Date:  2018-02-07       Impact factor: 9.825

5.  Oxidation of Organic Compounds Using Water as the Oxidant with H2 Liberation Catalyzed by Molecular Metal Complexes.

Authors:  Sayan Kar; David Milstein
Journal:  Acc Chem Res       Date:  2022-07-26       Impact factor: 24.466
  5 in total

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