Literature DB >> 28134945

Surface-selective direct 17O DNP NMR of CeO2 nanoparticles.

Michael A Hope1, David M Halat1, Pieter C M M Magusin1, Subhradip Paul2, Luming Peng3, Clare P Grey1.   

Abstract

Surface-selective direct 17O DNP has been demonstrated for the first time on CeO2 nanoparticles, for which the first three layers can be distinguished with high selectivity. Polarisation build-up curves show that the polarisation of the (sub-)surface sites builds up faster than the bulk, accounting for the remarkable surface selectivity.

Entities:  

Year:  2017        PMID: 28134945     DOI: 10.1039/c6cc10145c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  5 in total

Review 1.  17O NMR Spectroscopy in Lithium-Ion Battery Cathode Materials: Challenges and Interpretation.

Authors:  Euan N Bassey; Philip J Reeves; Ieuan D Seymour; Clare P Grey
Journal:  J Am Chem Soc       Date:  2022-10-06       Impact factor: 16.383

2.  Enabling Natural Abundance 17O Solid-State NMR by Direct Polarization from Paramagnetic Metal Ions.

Authors:  Daniel Jardón-Álvarez; Guy Reuveni; Adi Harchol; Michal Leskes
Journal:  J Phys Chem Lett       Date:  2020-06-25       Impact factor: 6.475

3.  Mapping the oxygen structure of γ-Al2O3 by high-field solid-state NMR spectroscopy.

Authors:  Qiang Wang; Wenzheng Li; Ivan Hung; Frederic Mentink-Vigier; Xiaoling Wang; Guodong Qi; Xiang Wang; Zhehong Gan; Jun Xu; Feng Deng
Journal:  Nat Commun       Date:  2020-07-17       Impact factor: 14.919

4.  Detection of the Surface of Crystalline Y2O3 Using Direct 89Y Dynamic Nuclear Polarization.

Authors:  Nick J Brownbill; Daniel Lee; Gaël De Paëpe; Frédéric Blanc
Journal:  J Phys Chem Lett       Date:  2019-06-12       Impact factor: 6.475

5.  Oxygen Vacancy Distribution in Yttrium-Doped Ceria from 89Y-89Y Correlations via Dynamic Nuclear Polarization Solid-State NMR.

Authors:  Daniel Jardón-Álvarez; Nitzan Kahn; Lothar Houben; Michal Leskes
Journal:  J Phys Chem Lett       Date:  2021-03-17       Impact factor: 6.475

  5 in total

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