| Literature DB >> 28121456 |
Weigao Hu1, Jiawei Li1, Yanli Xu1, Jianxiao Li1, Wanqing Wu1, Haiyang Liu1, Huanfeng Jiang1.
Abstract
A redox-neutral palladium-catalyzed N-O/C(sp3)-H functionalization of aryl oximes with isocyanides has been developed. Various pyrrole derivatives were prepared in good to excellent yields through oxime carbamate as a key intermediate and internal oxidant in this process. Furthermore, this transformation also features readily available starting materials, good functional group tolerance, and excellent regioselectivity.Entities:
Year: 2017 PMID： 28121456 DOI： 10.1021/acs.orglett.6b03852
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005