Literature DB >> 28106316

Ruthenium(II)-Catalyzed meta C-H Mono- and Difluoromethylations by Phosphine/Carboxylate Cooperation.

Zhixiong Ruan1, Shou-Kun Zhang1, Cuiju Zhu1, Paul Niklas Ruth2, Dietmar Stalke2, Lutz Ackermann1.   

Abstract

Ruthenium(II)-catalyzed meta-selective C-H (di)fluoromethylation was accomplished by phosphine and carboxylate cooperation. The remote C-H functionalization was characterized by ample substrate scope, thereby setting the stage for meta-(di)fluoromethylation through facile C-H cleavage.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−H activation; fluorine; meta-selectivity; phosphine; ruthenium

Year:  2017        PMID： 28106316     DOI： 10.1002/anie.201611595

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  9 in total

1.  Site-selective coupling of remote C(sp3)-H/meta-C(sp2)-H bonds enabled by Ru/photoredox dual catalysis and mechanistic studies.

Authors:  Hong-Chao Liu; Xiangtao Kong; Xiao-Ping Gong; Yuke Li; Zhi-Jie Niu; Xue-Ya Gou; Xue-Song Li; Yu-Zhao Wang; Wei-Yu Shi; Yan-Chong Huang; Xue-Yuan Liu; Yong-Min Liang
Journal:  Chem Sci       Date:  2022-04-12       Impact factor: 9.969

2.  Difluoroalkylation of Tertiary Amides and Lactams by an Iridium-Catalyzed Reductive Reformatsky Reaction.

Authors:  Phillip Biallas; Ken Yamazaki; Darren J Dixon
Journal:  Org Lett       Date:  2022-03-08       Impact factor: 6.072

3.  Ruthenium(II)-enabled para-selective C-H difluoromethylation of anilides and their derivatives.

Authors:  Chunchen Yuan; Lei Zhu; Changpeng Chen; Xiaolan Chen; Yong Yang; Yu Lan; Yingsheng Zhao
Journal:  Nat Commun       Date:  2018-03-22       Impact factor: 14.919

Review 4.  Recent advances in transition-metal-catalyzed incorporation of fluorine-containing groups.

Authors:  Xiaowei Li; Xiaolin Shi; Xiangqian Li; Dayong Shi
Journal:  Beilstein J Org Chem       Date:  2019-09-23       Impact factor: 2.883

Review 5.  Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds.

Authors:  Sebastián Barata-Vallejo; Al Postigo
Journal:  Molecules       Date:  2019-12-06       Impact factor: 4.411

6.  Distal Ruthenaelectro-Catalyzed meta-C-H Bromination with Aqueous HBr.

Authors:  Yulei Wang; Hendrik Simon; Xinran Chen; Zhipeng Lin; Shan Chen; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-16       Impact factor: 16.823

7.  Photo-Induced Ruthenium-Catalyzed Double Remote C(sp2 )-H / C(sp3 )-H Functionalizations by Radical Relay.

Authors:  Yulei Wang; Shan Chen; Xinran Chen; Agnese Zangarelli; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-10       Impact factor: 16.823

8.  Regiodivergent C-H and Decarboxylative C-C Alkylation by Ruthenium Catalysis: ortho versus meta Position-Selectivity.

Authors:  Korkit Korvorapun; Marc Moselage; Julia Struwe; Torben Rogge; Antonis M Messinis; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-25       Impact factor: 16.823

9.  Recyclable Ruthenium Catalyst for Distal meta-C-H Activation.

Authors:  Isaac Choi; Valentin Müller; Yanhui Wang; Kai Xue; Rositha Kuniyil; Loren B Andreas; Volker Karius; Johan G Alauzun; Lutz Ackermann
Journal:  Chemistry       Date:  2020-10-22       Impact factor: 5.236
  9 in total

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