| Literature DB >> 28105696 |
Sergey A Sapchenko1,2, Pavel A Demakov1,2, Denis G Samsonenko1,2, Danil N Dybtsev1,2, Martin Schröder1,3, Vladimir P Fedin1,2.
Abstract
The metal-organic framework (MOF) complex (H3 O)2 [Zn4 (ur)(Hfdc)2 (fdc)4 ] (1, ur=urotropine, H2 fdc=furan-2,5-dicarboxylic acid) incorporates cryptand-like cavities, which can be used to separate and detect Rb+ and Cs+ optically. This is the first example of the effective employment of a MOF material for optical detection of these cations.Entities:
Keywords: alkali metal recognition; cryptands; luminescent detectors; metal-organic frameworks; sensing
Year: 2017 PMID: 28105696 DOI: 10.1002/chem.201605895
Source DB: PubMed Journal: Chemistry ISSN: 0947-6539 Impact factor: 5.236