A photo-auxiliary approach - enabling excited state classical phototransformations with metal free visible light irradiation.

Most traditional photoreactions require UV light to yield the desired product. To address this issue, photoreaction of hydrazide based chromophores was evaluated with visible light using a metal free photocatalyst to afford photoproducts in high yields. This hydrazide functionality itself may be removed/modified after the photoreaction, highlighting its role as a "photo-auxiliary". A preliminary mechanistic model based on photophysical experiments is provided to highlight the generality of the strategy.