| Literature DB >> 28097754 |
Wei Li1, Alba Silipo2, Lotte Bettina Andersen Gersby3, Mari-Anne Newman3, Antonio Molinaro2, Biao Yu1.
Abstract
The unique α-(1→7)-bradyrhizoside linkages are constructed for the first time via judicious choice of the glycosylation partners and conditions, thus tetra- and penta-bradyrhizosides relevant to the peculiar O-antigen of Bradyrhizobium are synthesized, which are shown to adopt the defined right-handed helical conformations and to be unable to induce innate immune responses in plants.Entities:
Keywords: bradyrhizobium; carbohydrates; conformation; glycosylation; oligosaccharides
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Year: 2017 PMID： 28097754 DOI： 10.1002/anie.201610680
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336