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Literature DB >> 28097425

A personal perspective on the discovery of dioxygen adducts of copper and iron by Nobumasa Kitajima.

Abstract

Transition metal-dioxygen complexes have fascinated bioinorganic and inorganic chemists for over half a century. The late Nobumasa Kitajima was one of the very successful researchers in this field. Despite his short career (40 years old), he made many important contributions. This Commentary highlights his important accomplishments and how they have impacted subsequent work in this area.

Entities: Chemical Disease

Keywords: Copper; Dioxygen; Hydrotris(pyrazolyl)borate; Model complex; X-ray structure

Mesh：

Substances：

Year: 2017 PMID： 28097425 DOI： 10.1007/s00775-016-1432-1

Source DB: PubMed Journal: J Biol Inorg Chem ISSN： 0949-8257 Impact factor: 3.358

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References

31 in total

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A personal perspective on the discovery of dioxygen adducts of copper and iron by Nobumasa Kitajima.

Review 1. The crystal structure of catechol oxidase: new insight into the function of type-3 copper proteins.

2. Distorted tetrahedral nickel-nitrosyl complexes: spectroscopic characterization and electronic structure.

Review 3. Copper active sites in biology.

4. Spectroscopic and electronic structure studies of phenolate Cu(II) complexes: phenolate ring orientation and activation related to cofactor biogenesis.

Review 5. Evolution of molluscan hemocyanin structures.

6. Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues.

7. Electronic structure and reactivity of high-spin iron--alkyl- and--pterinperoxo complexes.

8. Conversion of carbon dioxide to oxalate by α-ketocarboxylatocopper(II) complexes.

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10. Structure determination of Panulirus interruptus haemocyanin at 3.2 A resolution. Successful phase extension by sixfold density averaging.