Literature DB >> 28075128

Pursuit of Record Breaking Energy Barriers: A Study of Magnetic Axiality in Diamide Ligated DyIII Single-Molecule Magnets.

Katie L M Harriman1, Jonathan L Brosmer2, Liviu Ungur3,4, Paula L Diaconescu2, Muralee Murugesu1.   

Abstract

DyIII single-ion magnets (SIMs) with strong axial donors and weak equatorial ligands are attractive model systems with which to harness the maximum magnetic anisotropy of DyIII ions. Utilizing a rigid ferrocene diamide ligand (NNTBS), a DyIII SIM, (NNTBS)DyI(THF)2, 1-Dy (NNTBS = fc(NHSitBuMe2)2, fc = 1,1'-ferrocenediyl), composed of a near linear arrangement of donor atoms, exhibits a large energy barrier to spin reversal (770.8 K) and magnetic blocking (14 K). The effects of the transverse ligands on the magnetic and electronic structure of 1-Dy were investigated through ab initio methods, eliciting significant magnetic axiality, even in the fourth Kramers doublet, thus demonstrating the potential of rigid diamide ligands in the design of new SIMs with defined magnetic axiality.

Entities:  

Year:  2017        PMID： 28075128     DOI： 10.1021/jacs.6b12374

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  The duality of electron localization and covalency in lanthanide and actinide metallocenes.

Authors:  Danil E Smiles; Enrique R Batista; Corwin H Booth; David L Clark; Jason M Keith; Stosh A Kozimor; Richard L Martin; Stefan G Minasian; David K Shuh; S Chantal E Stieber; Tolek Tyliszczak
Journal:  Chem Sci       Date:  2020-02-05       Impact factor: 9.825

2.  Transition metal redox switches for reversible "on/off" and "slow/fast" single-molecule magnet behaviour in dysprosium and erbium bis-diamidoferrocene complexes.

Authors:  Courtney M Dickie; Alexander L Laughlin; Joshua D Wofford; Nattamai S Bhuvanesh; Michael Nippe
Journal:  Chem Sci       Date:  2017-10-02       Impact factor: 9.825

3.  Magnetization relaxation in the single-ion magnet DySc2N@C80: quantum tunneling, magnetic dilution, and unconventional temperature dependence.

Authors:  D S Krylov; F Liu; A Brandenburg; L Spree; V Bon; S Kaskel; A U B Wolter; B Büchner; S M Avdoshenko; A A Popov
Journal:  Phys Chem Chem Phys       Date:  2018-04-19       Impact factor: 3.676

4.  Asymmetric Dinuclear Lanthanide(III) Complexes from the Use of a Ligand Derived from 2-Acetylpyridine and Picolinoylhydrazide: Synthetic, Structural and Magnetic Studies.

Authors:  Diamantoula Maniaki; Panagiota S Perlepe; Evangelos Pilichos; Sotirios Christodoulou; Mathieu Rouzières; Pierre Dechambenoit; Rodolphe Clérac; Spyros P Perlepes
Journal:  Molecules       Date:  2020-07-10       Impact factor: 4.411

5.  Reversible ON-OFF switching of single-molecule-magnetism associated with single-crystal-to-single-crystal structural transformation of a decanuclear dysprosium phosphonate.

Authors:  Haiquan Tian; Jing-Bu Su; Song-Song Bao; Mohamedally Kurmoo; Xin-Da Huang; Yi-Quan Zhang; Li-Min Zheng
Journal:  Chem Sci       Date:  2018-07-02       Impact factor: 9.825

6.  Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single-Ion Magnets.

Authors:  Angelos B Canaj; Sourav Dey; Emma Regincós Martí; Claire Wilson; Gopalan Rajaraman; Mark Murrie
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-22       Impact factor: 15.336

7.  Rigid N3O2-Pentadentate Ligand-Assisted Octacoordinate Mononuclear Ln(III) Complexes: Syntheses, Characterization, and Slow Magnetization Relaxation.

Authors:  Vaibhav Singh; Dhiraj Das; Srinivas Anga; Jean-Pascal Sutter; Vadapalli Chandrasekhar; Arun Kumar Bar
Journal:  ACS Omega       Date:  2022-07-13

8.  Thermo- and light-triggered reversible interconversion of dysprosium-anthracene complexes and their responsive optical, magnetic and dielectric properties.

Authors:  Xin-Da Huang; Ge-Hua Wen; Song-Song Bao; Jia-Ge Jia; Li-Min Zheng
Journal:  Chem Sci       Date:  2020-11-11       Impact factor: 9.825
  8 in total

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