Literature DB >> 28075115

Recent Methodologies That Exploit C-C Single-Bond Cleavage of Strained Ring Systems by Transition Metal Complexes.

Gabriele Fumagalli1, Steven Stanton1, John F Bower1.   

Abstract

In this review, synthetic and mechanistic aspects of key methodologies that exploit C-C single-bond cleavage of strained ring systems are highlighted. The focus is on transition-metal-catalyzed processes that are triggered by C-C bond activation and β-carbon elimination, with the review concentrating on developments from mid-2009 to mid-2016.

Entities:  

Year:  2017        PMID: 28075115     DOI: 10.1021/acs.chemrev.6b00599

Source DB:  PubMed          Journal:  Chem Rev        ISSN: 0009-2665            Impact factor:   60.622


  74 in total

Review 1.  Transition Metal-Mediated C-C Single Bond Cleavage: Making the Cut in Total Synthesis.

Authors:  Brian Wang; Melecio A Perea; Richmond Sarpong
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-24       Impact factor: 15.336

2.  Suzuki-Miyaura Coupling of Simple Ketones via Activation of Unstrained Carbon-Carbon Bonds.

Authors:  Ying Xia; Jianchun Wang; Guangbin Dong
Journal:  J Am Chem Soc       Date:  2018-04-17       Impact factor: 15.419

3.  Umpolung α-Silylation of Cyclopropyl Acetates via Low-Temperature Catalytic C-C Activation.

Authors:  Thirupataiah Avullala; Parham Asgari; Yuanda Hua; Apparao Bokka; Shawn G Ridlen; Kyungsuk Yum; H V Rasika Dias; Junha Jeon
Journal:  ACS Catal       Date:  2018-12-03       Impact factor: 13.084

4.  Intramolecular Acetyl Transfer to Olefins by Catalytic C-C Bond Activation of Unstrained Ketones.

Authors:  Zi-Qiang Rong; Hee Nam Lim; Guangbin Dong
Journal:  Angew Chem Int Ed Engl       Date:  2017-12-08       Impact factor: 15.336

5.  Kinetic Resolution via Rh-Catalyzed C-C Activation of Cyclobutanones at Room Temperature.

Authors:  Lin Deng; Yue Fu; Siu Yin Lee; Chengpeng Wang; Peng Liu; Guangbin Dong
Journal:  J Am Chem Soc       Date:  2019-10-02       Impact factor: 15.419

6.  Catalytic Ring Expansions of Cyclic Alcohols Enabled by Proton-Coupled Electron Transfer.

Authors:  Kuo Zhao; Kenji Yamashita; Joseph E Carpenter; Trevor C Sherwood; William R Ewing; Peter T W Cheng; Robert R Knowles
Journal:  J Am Chem Soc       Date:  2019-05-23       Impact factor: 15.419

7.  Catalytic Enantioselective Synthesis of Cyclobutenes from Alkynes and Alkenyl Derivatives.

Authors:  Mahesh M Parsutkar; Vinayak Vishnu Pagar; T V RajanBabu
Journal:  J Am Chem Soc       Date:  2019-09-12       Impact factor: 15.419

8.  Ruthenium-catalyzed insertion of adjacent diol carbon atoms into C-C bonds: Entry to type II polyketides.

Authors:  Matthias Bender; Ben W H Turnbull; Brett R Ambler; Michael J Krische
Journal:  Science       Date:  2017-08-25       Impact factor: 47.728

9.  Thermal Hetero-Diels-Alder Reaction of Benzocyclobutenones with Isatins To Form 2-Oxindole Spirolactones.

Authors:  Thomas Wurm; Ben W H Turnbull; Brett R Ambler; Michael J Krische
Journal:  J Org Chem       Date:  2017-11-22       Impact factor: 4.354

10.  A ring expansion strategy towards diverse azaheterocycles.

Authors:  Ruirui Li; Bo Li; Hongpeng Zhang; Cheng-Wei Ju; Ying Qin; Xiao-Song Xue; Dongbing Zhao
Journal:  Nat Chem       Date:  2021-07-19       Impact factor: 24.427

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