Literature DB >> 28066996

Selective Hydrogenation of Nitriles to Primary Amines by using a Cobalt Phosphine Catalyst.

Rosa Adam1, Charles Beromeo Bheeter1, Jose R Cabrero-Antonino1, Kathrin Junge1, Ralf Jackstell1, Matthias Beller1.   

Abstract

A general procedure for the catalytic hydrogenation of nitriles to primary amines by using a non-noble metal-based system is presented. Co(acac)3 in combination with tris[2-(dicyclohexylphosphino)ethyl]phosphine efficiently catalyzes the selective hydrogenation of a wide range of (hetero)aromatic and aliphatic nitriles to give the corresponding amines.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  cobalt; homogeneous catalysis; hydrogenation; nitrile; phosphines

Mesh：

Substances：

Year:  2017        PMID： 28066996     DOI： 10.1002/cssc.201601843

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  11 in total

1.  Nickel-Catalyzed Transfer Hydrogenation of Benzonitriles with 2-Propanol and 1,4-Butanediol as the Hydrogen Source.

Authors:  Jorge A Garduño; Juventino J García
Journal:  ACS Omega       Date:  2017-05-26

2.  Old Concepts, New Application - Additive-Free Hydrogenation of Nitriles Catalyzed by an Air Stable Alkyl Mn(I) Complex.

Authors:  Stefan Weber; Luis F Veiros; Karl Kirchner
Journal:  Adv Synth Catal       Date:  2019-10-28       Impact factor: 5.837

3.  Facile synthesis of supported Ru-Triphos catalysts for continuous flow application in selective nitrile reduction.

Authors:  Robert Konrath; Frank J L Heutz; Norbert Steinfeldt; Nils Rockstroh; Paul C J Kamer
Journal:  Chem Sci       Date:  2019-07-23       Impact factor: 9.825

4.  Ligand-enabled and magnesium-activated hydrogenation with earth-abundant cobalt catalysts.

Authors:  Bo Han; Miaomiao Zhang; Hongmei Jiao; Haojie Ma; Jijiang Wang; Yuqi Zhang
Journal:  RSC Adv       Date:  2021-12-15       Impact factor: 4.036

5.  Cobalt-Catalyzed Asymmetric Hydrogenation of Enamides: Insights into Mechanisms and Solvent Effects.

Authors:  Ljiljana Pavlovic; Lauren N Mendelsohn; Hongyu Zhong; Paul J Chirik; Kathrin H Hopmann
Journal:  Organometallics       Date:  2022-07-25       Impact factor: 3.837

6.  Nanoparticles and single atoms of cobalt synergistically enabled low-temperature reductive amination of carbonyl compounds.

Authors:  Bingxiao Zheng; Jiao Xu; Jinliang Song; Haihong Wu; Xuelei Mei; Kaili Zhang; Wanying Han; Wei Wu; Mingyuan He; Buxing Han
Journal:  Chem Sci       Date:  2022-07-08       Impact factor: 9.969

7.  Cobalt-catalysed reductive C-H alkylation of indoles using carboxylic acids and molecular hydrogen.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-07-26       Impact factor: 9.825

8.  Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Mattes Holsten; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-06-12       Impact factor: 9.825

9.  Pd-CuFe Catalyst for Transfer Hydrogenation of Nitriles: Controllable Selectivity to Primary Amines and Secondary Amines.

Authors:  Lei Liu; Yuhong Liu; Yongjian Ai; Jifan Li; Junjie Zhou; Zhibo Fan; Hongjie Bao; Ruihang Jiang; Zenan Hu; Jingting Wang; Ke Jing; Yue Wang; Qionglin Liang; Hongbin Sun
Journal:  iScience       Date:  2018-09-19

10.  A cobalt phosphide catalyst for the hydrogenation of nitriles.

Authors:  Takato Mitsudome; Min Sheng; Ayako Nakata; Jun Yamasaki; Tomoo Mizugaki; Koichiro Jitsukawa
Journal:  Chem Sci       Date:  2020-06-09       Impact factor: 9.825
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