Literature DB >> 28055144

Systematic Study of Open-Shell Trigonal Pyramidal Transition-Metal Complexes with a Rigid-Ligand Scaffold.

Dawid Pinkowicz1,2, Francisco J Birk2, Michał Magott1, Kelsey Schulte2, Kim R Dunbar2.   

Abstract

A family of distorted trigonal pyramidal transition-metal complexes [MII (N3 N)Li(THF)] (M=Mn, Fe, Co, Ni) have been studied as candidates for mononuclear single-molecule magnets. Magnetic anisotropy of the family depends on the electronic configuration of the central ion, with the Co analogue exhibiting pronounced SMM behavior.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  coordination chemistry; magnetic properties; nanomagnetism; single-molecule magnets; trigonal pyramidal geometry

Year:  2017        PMID： 28055144     DOI： 10.1002/chem.201605528

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  2 in total

1.  Synthesis of FeIII and FeIV Cyanide Complexes Using Hypervalent Iodine Reagents as Cyano-Transfer One-Electron Oxidants.

Authors:  Charafa Souilah; Sergio A V Jannuzzi; Derya Demirbas; Sergei Ivlev; Marcel Swart; Serena DeBeer; Alicia Casitas
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-29       Impact factor: 16.823

2.  Orbital energy mismatch engenders high-spin ground states in heterobimetallic complexes.

Authors:  Scott C Coste; Tyler J Pearson; Alison B Altman; Ryan A Klein; Brian A Finney; Michael Y Hu; E Ercan Alp; Bess Vlaisavljevich; Danna E Freedman
Journal:  Chem Sci       Date:  2020-09-01       Impact factor: 9.825
  2 in total

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