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Literature DB >> 28044173

Preparation and use of DMF-stabilized iridium nanoclusters as methylation catalysts using methanol as the C1 source.

Kei Oikawa¹, Satoshi Itoh¹, Hiroki Yano¹, Hideya Kawasaki¹, Yasushi Obora¹.

Abstract

We report methylations of alcohols and anilines catalyzed by DMF-stabilized Ir nanoclusters using methanol as the C1 source. The DMF-stabilized Ir nanoclusters were prepared in one step and have diameters of 1-1.5 nm. They react in a borrowing-hydrogen reaction and are efficient methylation catalysts (TON up to 310 000).

Entities: Chemical

Year: 2017 PMID： 28044173 DOI： 10.1039/c6cc09279a

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

13 in total

1. Fluorescent iridium nanoclusters for selective determination of chromium(VI).

Authors: Malin Cui; Chan Wang; Dapeng Yang; Qijun Song
Journal: Mikrochim Acta Date: 2017-12-02 Impact factor: 5.833

Review 2. Borrowing Hydrogen for Organic Synthesis.

Authors: Benjamin G Reed-Berendt; Daniel E Latham; Mubarak B Dambatta; Louis C Morrill
Journal: ACS Cent Sci Date: 2021-03-25 Impact factor: 14.553

3. Synthesis and Characterization of N,N-Dimethylformamide-Protected Palladium Nanoparticles and Their Use in the Suzuki-Miyaura Cross-Coupling Reaction.

Authors: Junya Ishida; Masato Nakatsuji; Tatsuki Nagata; Hideya Kawasaki; Takeyuki Suzuki; Yasushi Obora
Journal: ACS Omega Date: 2020-04-16

4. Manganese-Catalyzed β-Methylation of Alcohols by Methanol.

Authors: Martin Schlagbauer; Fabian Kallmeier; Torsten Irrgang; Rhett Kempe
Journal: Angew Chem Int Ed Engl Date: 2019-12-12 Impact factor: 15.336

5. Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes.

Authors: Tatsuki Nagata; Takeru Inoue; Xianjin Lin; Shinya Ishimoto; Seiya Nakamichi; Hideo Oka; Ryota Kondo; Takeyuki Suzuki; Yasushi Obora
Journal: RSC Adv Date: 2019-06-03 Impact factor: 4.036

10. Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols.

Authors: Yao Cui; Jixian Wang; Lei Yu; Ying Xu; David J Young; Haiyan Li; Hongxi Li
Journal: Polymers (Basel) Date: 2022-01-07 Impact factor: 4.329

Preparation and use of DMF-stabilized iridium nanoclusters as methylation catalysts using methanol as the C1 source.

1. Fluorescent iridium nanoclusters for selective determination of chromium(VI).

Review 2. Borrowing Hydrogen for Organic Synthesis.

3. Synthesis and Characterization of N,N-Dimethylformamide-Protected Palladium Nanoparticles and Their Use in the Suzuki-Miyaura Cross-Coupling Reaction.

4. Manganese-Catalyzed β-Methylation of Alcohols by Methanol.

5. Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes.

6. Carbon monoxide and hydrogen (syngas) as a C1-building block for selective catalytic methylation.

Review 7. Recent Uses of N,N-Dimethylformamide and N,N-Dimethylacetamide as Reagents.

8. Iron-Catalyzed Borrowing Hydrogen β-C(sp³)-Methylation of Alcohols.

9. Manganese(I)-Catalyzed β-Methylation of Alcohols Using Methanol as C₁ Source.

10. Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols.