| Literature DB >> 28032281 |
Ibrahim Uyanik1, Mehmet Oguz2, Asif Ali Bhatti2,3, Arzu Uyanik2, Mustafa Yilmaz4.
Abstract
In this study, we report the synthesis of new Schiff base E-1-(((1-benzylpiperidin-4-yl)imino)methyl)naphthalenee-2-ol (L) and evaluation of its fluorescence response toward Cu2+ ion. Preliminary, solvent effect, metal selectivity and metal ligand ratio were analyzed through UV-Visible study. Fluorescence response toward Cu2+ was carried to assess the fluorescent property of synthesized Schiff base. The probe exhibited a higher fluorescence enhancement in the presence of Cu2+ over other metal ions (Ni2+, Zn2+, Hg2+, Co2+, Cd2+, Al3+, Fe2+, and Pb2+). The binding stoichiometry between L and Cu2+ has been investigated using Job's plot and Benesi-Hildebrand equation and it was found that ligand L can form 1:1 L-Cu2+ complex with binding constant (K a) of 4 × 104 LM-1.Entities:
Keywords: Binding constant; Copper; Fluorescence; Piperidine; Schiff base
Year: 2016 PMID: 28032281 DOI: 10.1007/s10895-016-2013-y
Source DB: PubMed Journal: J Fluoresc ISSN: 1053-0509 Impact factor: 2.217