| Literature DB >> 27999832 |
Anthony F Hill1, Richard Y Kong1.
Abstract
Bromination of the carbyne complexes [W([triple bond, length as m-dash]CR)Br(CO)2(dcpe)] (R = Ph, SiPh3; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W([triple bond, length as m-dash]CPh)Br3(dcpe)] and [W([triple bond, length as m-dash]CBr)Br3(dcpe)], the latter via an unprecedented bromodesilylation process.Entities:
Year: 2017 PMID： 27999832 DOI： 10.1039/c6cc08946a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222