Literature DB >> 27990539

Reversible formylborane/SO2 coupling at a frustrated Lewis pair framework.

Ke-Yin Ye1, Markus Bursch2, Zheng-Wang Qu2, Constantin G Daniliuc1, Stefan Grimme2, Gerald Kehr1, Gerhard Erker1.   

Abstract

Carbon monoxide is reduced by HB(C6F5)2 at the Mes2PCH2CH2B(C6F5)2 P/B FLP template to give the respective FLP stabilized (η2-formyl)borane product 2. This adds sulfur dioxide by insertion of a SO bond into the three-membered ring to give the P/B FLP coordinated SO2 adduct 9.

Entities:  

Year:  2017        PMID: 27990539     DOI: 10.1039/c6cc07071j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Fully Automated Quantum-Chemistry-Based Computation of Spin-Spin-Coupled Nuclear Magnetic Resonance Spectra.

Authors:  Stefan Grimme; Christoph Bannwarth; Sebastian Dohm; Andreas Hansen; Jana Pisarek; Philipp Pracht; Jakob Seibert; Frank Neese
Journal:  Angew Chem Int Ed Engl       Date:  2017-10-11       Impact factor: 15.336

2.  Single Electron Transfer to Diazomethane-Borane Adducts Prompts C-H Bond Activations.

Authors:  Levy L Cao; Jiliang Zhou; Zheng-Wang Qu; Douglas W Stephan
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-30       Impact factor: 15.336

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.