| Literature DB >> 27990522 |
Kasuni C Boteju1, Arkady Ellern1, Aaron D Sadow1.
Abstract
A β-SiH functionalized benzyl anion [C(SiHMe2)2Ph]- is obtained by deprotonation of HC(SiHMe2)2Ph with KCH2Ph or by reaction of KOtBu and (Me2HSi)3CPh; LnI3(THF)n and three equivalents of this carbanion combine to provide homoleptic tris(alkyl)lanthanide compounds Ln{C(SiHMe2)2Ph}3 (Ln = La, Ce, Pr, Nd) containing secondary metal-ligand interactions.Entities:
Year: 2017 PMID： 27990522 DOI： 10.1039/c6cc09304c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222