| Literature DB >> 27987965 |
Binyan Huang1, Yunguo Liu2, Bin Li3, Shaobo Liu4, Guangming Zeng1, Zhiwei Zeng1, Xiaohua Wang1, Qimeng Ning1, Bohong Zheng5, Chunping Yang1.
Abstract
Fe3O4@SiO2-Chitosan/GO (MSCG) nanocomposite was investigated by various techniques (SEM, TEM, XRD, VSM, FT-IR, XPS) for the removal of tetracycline (TC). Effects of pH, zeta potential and initial contaminant concentration were studied in detail. Four background cations (Na+, K+, Ca2+ and Mg2+) with a concentration of 0.01M showed little influence on the TC adsorption at the studied pH range while the divalent heavy metal cation Cu(II) could significantly enhance the adsorption. The results indicated that the highest adsorption capacity of TC were 183.47mmol/kg and 67.57mmol/kg on MSCG with and without Cu(II), respectively. According to mechanism investigation for the adsorption of TC by pH impact study and XPS analysis, besides electrostatic interaction and π-π interactions, the Cu(II) also acts as a bridge between TC and MSCG, which significantly improve the adsorption of TC. This study provided valuable guidance and effective method for the removal of TC from aquatic environments.Entities:
Keywords: Adsorption; Chitosan; Cu(II); Graphene oxide; Tetracycline (TC)
Mesh：
Substances：
Year: 2016 PMID： 27987965 DOI： 10.1016/j.carbpol.2016.10.025
Source DB: PubMed Journal: Carbohydr Polym ISSN： 0144-8617 Impact factor: 9.381