Literature DB >> 27981629

Gold(III) Triggered Transformations of 22-Methyl-m-benziporphyrin Involving an Effective Contraction of Benzene to Cyclopentadiene.

Karolina Hurej1, Miłosz Pawlicki1, Lechosław Latos-Grażyński1.   

Abstract

A structurally prearranged carbaporphyrin, 22-methyl-m-benziporphyrin, provided the perfect macrocyclic platform to form gold(III) 22-methyl-m-benziporphyrin, which facilitates the specific m-benzene ring contraction yielding gold(III) 21-methyl 21-carbaporphyrin with remarkably high yield.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  benzene; carbaporphyrinoid; contraction; gold; porphyrin

Year:  2016        PMID： 27981629     DOI： 10.1002/chem.201604458

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  1 in total

1.  UO2 2+-mediated ring contraction of pyrihexaphyrin: synthesis of a contracted expanded porphyrin-uranyl complex.

Authors:  James T Brewster; Harrison D Root; Daniel Mangel; Adam Samia; Hadiqa Zafar; Adam C Sedgwick; Vincent M Lynch; Jonathan L Sessler
Journal:  Chem Sci       Date:  2019-04-30       Impact factor: 9.825
  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.