Literature DB >> 27966714

Transition metal catalysis-a unique road map in the stereoselective synthesis of 1,3-polyols.

Pradeep Kumar1, Divya Tripathi1, Brijesh M Sharma1, Namrata Dwivedi1.   

Abstract

The present review summarizes recent diverse reactions employed in the formation of 1,3-polyols providing an overview of the mechanistic pathway and the enantioselectivity obtained, in terms of the properties of transition metals directly involved in the catalytic transformations and their interaction with various ligands.

Entities:  

Year:  2017        PMID： 27966714     DOI： 10.1039/c6ob01925k

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  8 in total

1.  Direct Conversion of Primary Alcohols to 1,2-Amino Alcohols: Enantioselective Iridium-Catalyzed Carbonyl Reductive Coupling of Phthalimido-Allene via Hydrogen Auto-Transfer.

Authors:  Kim Spielmann; Ming Xiang; Leyah A Schwartz; Michael J Krische
Journal:  J Am Chem Soc       Date:  2019-08-29       Impact factor: 15.419

2.  Synthetic utility of one-pot chemoenzymatic reaction sequences.

Authors:  Tyler J Doyon; Alison R H Narayan
Journal:  Synlett       Date:  2019-06-06       Impact factor: 2.454

3.  Successive Nucleophilic and Electrophilic Allylation for the Catalytic Enantioselective Synthesis of 2,4-Disubstituted Pyrrolidines.

Authors:  Guoshun Luo; Ming Xiang; Michael J Krische
Journal:  Org Lett       Date:  2019-02-28       Impact factor: 6.005

Review 4.  Feedstock Reagents in Metal-Catalyzed Carbonyl Reductive Coupling: Minimizing Preactivation for Efficiency in Target-Oriented Synthesis.

Authors:  Rosalie S Doerksen; Cole C Meyer; Michael J Krische
Journal:  Angew Chem Int Ed Engl       Date:  2019-07-26       Impact factor: 15.336

5.  Total Synthesis of Clavosolide A via Asymmetric Alcohol-Mediated Carbonyl Allylation: Beyond Protecting Groups or Chiral Auxiliaries in Polyketide Construction.

Authors:  James M Cabrera; Michael J Krische
Journal:  Angew Chem Int Ed Engl       Date:  2019-06-24       Impact factor: 15.336

6.  Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier.

Authors:  Seung Wook Kim; Wandi Zhang; Michael J Krische
Journal:  Acc Chem Res       Date:  2017-08-09       Impact factor: 22.384

7.  Catalytic Enantioselective Allylations of Acetylenic Aldehydes via 2-Propanol-Mediated Reductive Coupling.

Authors:  Gilmar A Brito; Franco Della-Felice; Guoshun Luo; Alexander S Burns; Ronaldo A Pilli; Scott D Rychnovsky; Michael J Krische
Journal:  Org Lett       Date:  2018-06-25       Impact factor: 6.005

8.  Chiral Syn-1,3-diol Derivatives via a One-Pot Diastereoselective Carboxylation/ Bromocyclization of Homoallylic Alcohols.

Authors:  Guanxin Huang; Minjie Liu; Fangjun Xiong; Ge Meng; Yuan Tao; Yan Wu; Haihui Peng; Fener Chen
Journal:  iScience       Date:  2018-11-09
  8 in total

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