Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Mixed valence copper-sulfur clusters of highest nuclearity: a Cu8 wheel and a Cu16 nanoball.

Literature DB >> 27966706

Mixed valence copper-sulfur clusters of highest nuclearity: a Cu₈ wheel and a Cu₁₆ nanoball.

Ram Chandra Maji¹, Partha Pratim Das², Anirban Bhandari¹, Saikat Mishra¹, Milan Maji¹, Kamran B Ghiassi³, Marilyn M Olmstead³, Apurba K Patra¹.

Abstract

Fully spin delocalized mixed valence copper-sulfur clusters, 1 and 2, supported by μ4-sulfido and NSthiol donor ligands are synthesized and characterized. Wheel shaped 1 consists of Cu2S2 units. The unprecedented nanoball 2 can be described as S@Cu4(tetrahedron)@O6(octahedron)@Cu12S12(cage) consisting of both Cu2S2 and (μ4-S)Cu4 units. The Cu2S2 and (μ4-S)Cu4 units resemble biological CuA and CuZ sites respectively.

Entities: Chemical Species

Year: 2017 PMID： 27966706 DOI： 10.1039/c6cc08301c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

1 in total

1. Mercaptothiacalixarenes Steer 24 Copper(I) Centers to form a Hollow-Sphere Structure Featuring Cu₂ S₂ Motifs with Exceptionally Short Cu⋅⋅⋅Cu Distances.

Authors: Nicolas Frank; André Dallmann; Beatrice Braun-Cula; Christian Herwig; Christian Limberg
Journal: Angew Chem Int Ed Engl Date: 2020-03-03 Impact factor: 15.336

1 in total

Mixed valence copper-sulfur clusters of highest nuclearity: a Cu8 wheel and a Cu16 nanoball.

1. Mercaptothiacalixarenes Steer 24 Copper(I) Centers to form a Hollow-Sphere Structure Featuring Cu2 S2 Motifs with Exceptionally Short Cu⋅⋅⋅Cu Distances.

Mixed valence copper-sulfur clusters of highest nuclearity: a Cu₈ wheel and a Cu₁₆ nanoball.

1. Mercaptothiacalixarenes Steer 24 Copper(I) Centers to form a Hollow-Sphere Structure Featuring Cu₂ S₂ Motifs with Exceptionally Short Cu⋅⋅⋅Cu Distances.