| Literature DB >> 27958607 |
Ana I Ojeda-Amador1, Antonio J Martínez-Martínez1, Alan R Kennedy1, David R Armstrong1, Charles T O'Hara1.
Abstract
After isolating an unusual binuclear, but monosolvated NaHMDS complex [{(R,R)-TMCDA}·(NaHMDS)2]∞ which polymerises via intermolecular electrostatic NaMeHMDS interactions, further (R,R)-TMCDA was added to produce the discrete binuclear amide [{κ2-(R,R)-TMCDA}·(NaHMDS)2{κ1-(R,R)-TMCDA}], whose salient feature is the unique monodentate coordination of one of the chiral diamine ligands.Entities:
Year: 2016 PMID： 27958607 DOI： 10.1039/c6cc07190b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222