Literature DB >> 27936644

Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles.

Zhiwei Jiao1, Kwok Wei Chee1, Jianrong Steve Zhou1.   

Abstract

Asymmetric arylation of alkylnitriles forms quaternary stereocenters in good enantiocontrol for the first time. A lithium heterodimer consisting of an alkylnitrile anion and a disilylamide ion is the actual species responsible for the stereodetermining transmetalation in the catalytic cycle.

Entities:  

Year:  2016        PMID： 27936644     DOI： 10.1021/jacs.6b11610

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Enantioselective Olefin Hydrocyanation without Cyanide.

Authors:  Alexander W Schuppe; Gustavo M Borrajo-Calleja; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2019-11-18       Impact factor: 15.419

2.  Synthesis of benzannelated sultams by intramolecular Pd-catalyzed arylation of tertiary sulfonamides.

Authors:  Valentin A Rassadin; Mirko Scholz; Anastasiia A Klochkova; Armin de Meijere; Victor V Sokolov
Journal:  Beilstein J Org Chem       Date:  2017-09-12       Impact factor: 2.883

3.  Synergistic Pd/Cu-catalyzed enantioselective Csp2-F bond alkylation of fluoro-1,3-dienes with aldimine esters.

Authors:  Huimin Yu; Qinglong Zhang; Weiwei Zi
Journal:  Nat Commun       Date:  2022-05-05       Impact factor: 17.694

4.  About the selectivity and reactivity of active nickel electrodes in C-C coupling reactions.

Authors:  Sebastian B Beil; Manuel Breiner; Lara Schulz; Aaron Schüll; Timo Müller; Dieter Schollmeyer; Alexander Bomm; Michael Holtkamp; Uwe Karst; Wolfgang Schade; Siegfried R Waldvogel
Journal:  RSC Adv       Date:  2020-04-08       Impact factor: 3.361
  4 in total

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