| Literature DB >> 27934469 |
Changduo Pan1,2, Yu Chen1, Shuai Song1, Lei Li1, Jin-Tao Yu2.
Abstract
The oxidative difunctionalization of aryl alkynoates with alphatic aldehydes as a cheap and abundant alkyl radical source was developed, providing a variety of trisubstituted alkenes in moderate to good yields. In this reaction, radical decarbonylative alkylation of C-C triple bond, 1,4-aryl migration, and decarboxylation were involved under metal-free conditions.Entities:
Year: 2016 PMID： 27934469 DOI： 10.1021/acs.joc.6b02451
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354