Organic-Inorganic Nanocomposites via Self-Assembly of an Amphiphilic Triblock Copolymer Bearing a Poly(butadiene-g-POSS) Subchain in Epoxy Thermosets: Morphologies, Surface Hydrophobicity, and Dielectric Properties.

Organic-inorganic nanocomposites composed of polyhedral oligomeric silsesquioxane (POSS) and epoxy resin were prepared via self-assembly of an amphiphilic triblock copolymer bearing a poly(POSS) midblock in epoxy thermosets. First, this organic-inorganic amphiphilic triblock copolymer was synthesized via hydrosilylation of heptaphenylhydro POSS with an existing triblock copolymer containing a short polybutadiene midblock. It was found that this novel amphiphilic block copolymer can self-assemble into nanophases in epoxy thermosets. In the presence of preformed nanophases, the curing reaction was performed, and the organic-inorganic nanocomposites containing poly(POSS) microdomains were thus obtained. Compared with plain epoxy, the as-obtained thermosets exhibited enhanced surface hydrophobicity; the enhanced surface hydrophobicity is attributed to enrichment of the POSS component at the surface of the materials. Owing to the formation of poly(POSS) microdomains, the dielectric constants of the materials significantly reduced, whereas the dielectric loss remained almost unchanged.