Literature DB >> 27934006

Alkyl Bromides as Mild Hydride Sources in Ni-Catalyzed Hydroamidation of Alkynes with Isocyanates.

Xueqiang Wang1, Masaki Nakajima1, Eloisa Serrano1, Ruben Martin1,2.   

Abstract

A catalytic hydroamidation of alkynes with isocyanates using alkyl bromides as hydride sources has been developed. The method turns parasitic β-hydride elimination into a strategic advantage, rapidly affording acrylamides with excellent chemo- and regioselectivity.

Entities:  

Year:  2016        PMID： 27934006     DOI： 10.1021/jacs.6b10351

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  Nickel-catalyzed difunctionalization of allyl moieties using organoboronic acids and halides with divergent regioselectivities.

Authors:  Wanfang Li; Jie Kang Boon; Yu Zhao
Journal:  Chem Sci       Date:  2017-10-26       Impact factor: 9.825

Review 2.  Walking Metals for Remote Functionalization.

Authors:  Heiko Sommer; Francisco Juliá-Hernández; Ruben Martin; Ilan Marek
Journal:  ACS Cent Sci       Date:  2018-02-08       Impact factor: 14.553

3.  Amide synthesis via nickel-catalysed reductive aminocarbonylation of aryl halides with nitroarenes.

Authors:  Chi Wai Cheung; Marten Leendert Ploeger; Xile Hu
Journal:  Chem Sci       Date:  2017-11-06       Impact factor: 9.825

4.  Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes.

Authors:  Lu Zhou; Chuan Zhu; Peijia Bi; Chao Feng
Journal:  Chem Sci       Date:  2018-11-09       Impact factor: 9.825

5.  Iridium-Catalyzed Hydrochlorination and Hydrobromination of Alkynes by Shuttle Catalysis.

Authors:  Peng Yu; Alessandro Bismuto; Bill Morandi
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-16       Impact factor: 15.336

6.  Reductive Elimination from Sterically Encumbered Ni-Polypyridine Complexes.

Authors:  Craig S Day; Stephanie J Ton; Ryan T McGuire; Cina Foroutan-Nejad; Ruben Martin
Journal:  Organometallics       Date:  2022-09-21       Impact factor: 3.837

7.  syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis.

Authors:  Lei Guo; Fan Song; Shengqing Zhu; Huan Li; Lingling Chu
Journal:  Nat Commun       Date:  2018-10-31       Impact factor: 14.919
  7 in total

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