| Literature DB >> 27933895 |
Birakishore Padhi1,2, G Sudhakar Reddy1,2, Debendra K Mohapatra1,2.
Abstract
A unified and efficient synthetic route for both tetraketide (1) and cryptorigidifoliol I (2) has been devised successfully from commercially available starting materials in 11 and 17 steps, with 16% and 11% overall yields, respectively. Highlights of the syntheses involved sequential Lewis acid-catalyzed highly regio- and diastereoselective allylations and intramolecular Mitsunobu lactonization.Entities:
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Year: 2016 PMID： 27933895 DOI： 10.1021/acs.jnatprod.6b00443
Source DB: PubMed Journal: J Nat Prod ISSN： 0163-3864 Impact factor: 4.050