Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Switchable Surface Hydrophobicity-Hydrophilicity of a Metal-Organic Framework.

Literature DB >> 27891752

Switchable Surface Hydrophobicity-Hydrophilicity of a Metal-Organic Framework.

Sabina Rodríguez-Hermida¹, Min Ying Tsang², Claudia Vignatti¹, Kyriakos C Stylianou¹, Vincent Guillerm¹, Javier Pérez-Carvajal¹, Francesc Teixidor², Clara Viñas², Duane Choquesillo-Lazarte³, Cristóbal Verdugo-Escamilla³, Inmaculada Peral⁴, Jordi Juanhuix⁵, Albert Verdaguer¹, Inhar Imaz¹, Daniel Maspoch^1,6, José Giner Planas².

Abstract

Materials with surfaces that can be switched from high/superhydrophobicity to superhydrophilicity are useful for myriad applications. Herein, we report a metal-organic framework (MOF) assembled from ZnII ions, 1,4-benzenedicarboxylate, and a hydrophobic carborane-based linker. The MOF crystal-surface can be switched between hydrophobic and superhydrophilic through a chemical treatment to remove some of the building blocks.

Entities: Chemical Gene

Keywords: carboranes; hydrophilicity; hydrophobicity; metal-organic frameworks; surface chemistry

Year: 2016 PMID： 27891752 DOI： 10.1002/anie.201609295

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

6 in total

1. Water-Stable Carborane-Based Eu³⁺/Tb³⁺ Metal-Organic Frameworks for Tunable Time-Dependent Emission Color and Their Application in Anticounterfeiting Bar-Coding.

Authors: Zhen Li; Rosario Núñez; Mark E Light; Eliseo Ruiz; Francesc Teixidor; Clara Viñas; Daniel Ruiz-Molina; Claudio Roscini; José Giner Planas
Journal: Chem Mater Date: 2022-04-29 Impact factor: 10.508

2. Expansion of the (BB) 〉metallacycle with coinage metal cations: formation of B-M-Ru-B (M = Cu, Ag, Au) dimetalacyclodiboryls.

Authors: Bennett J Eleazer; Mark D Smith; Alexey A Popov; Dmitry V Peryshkov
Journal: Chem Sci Date: 2018-02-05 Impact factor: 9.825

Switchable Surface Hydrophobicity-Hydrophilicity of a Metal-Organic Framework.

1. Water-Stable Carborane-Based Eu³⁺/Tb³⁺ Metal-Organic Frameworks for Tunable Time-Dependent Emission Color and Their Application in Anticounterfeiting Bar-Coding.

2. Expansion of the (BB) 〉metallacycle with coinage metal cations: formation of B-M-Ru-B (M = Cu, Ag, Au) dimetalacyclodiboryls.

3. A Reversible Phase Transition of 2D Coordination Layers by B-H∙∙∙Cu(II) Interactions in a Coordination Polymer.

4. Efficient access to amides of the carborane carboxylic acid [1-(COOH)-CB₁₁H₁₁]^.

5. Highly selective palladium-catalyzed one-pot, five-fold B-H/C-H cross coupling of monocarboranes with alkenes.

Review 6. Improving MOF stability: approaches and applications.

Switchable Surface Hydrophobicity-Hydrophilicity of a Metal-Organic Framework.

1. Water-Stable Carborane-Based Eu3+/Tb3+ Metal-Organic Frameworks for Tunable Time-Dependent Emission Color and Their Application in Anticounterfeiting Bar-Coding.

2. Expansion of the (BB) 〉metallacycle with coinage metal cations: formation of B-M-Ru-B (M = Cu, Ag, Au) dimetalacyclodiboryls.

3. A Reversible Phase Transition of 2D Coordination Layers by B-H∙∙∙Cu(II) Interactions in a Coordination Polymer.

4. Efficient access to amides of the carborane carboxylic acid [1-(COOH)-CB11H11].

5. Highly selective palladium-catalyzed one-pot, five-fold B-H/C-H cross coupling of monocarboranes with alkenes.

Review 6. Improving MOF stability: approaches and applications.

1. Water-Stable Carborane-Based Eu³⁺/Tb³⁺ Metal-Organic Frameworks for Tunable Time-Dependent Emission Color and Their Application in Anticounterfeiting Bar-Coding.

4. Efficient access to amides of the carborane carboxylic acid [1-(COOH)-CB₁₁H₁₁]^.