| Literature DB >> 27886413 |
Xuemei Zhou1, Ning Liu1, Jochen Schmidt2, Axel Kahnt3, Andres Osvet4, Stefan Romeis2, Eva M Zolnhofer5, Venkata Ramana Reddy Marthala6, Dirk M Guldi3, Wolfgang Peukert2, Martin Hartmann6, Karsten Meyer5, Patrik Schmuki1.
Abstract
Ball milling TiO2 anatase together with TiH2 can create an effective photocatalyst. The process changes the lattice and electronic structure of anatase. Lattice deformation created by mechanical impact combined with hydride incorporation yield electronic gap-states close to the conduction band of anatase. These provide longer lifetimes of photogenerated charge carriers and lead to an intrinsic cocatalytic activation of anatase for H2 evolution.Entities:
Keywords: anatase; ball milling; hydrogen evolution; photocatalysis; titanium hydride
Year: 2016 PMID: 27886413 DOI: 10.1002/adma.201604747
Source DB: PubMed Journal: Adv Mater ISSN: 0935-9648 Impact factor: 30.849