Literature DB >> 27886413

Noble-Metal-Free Photocatalytic Hydrogen Evolution Activity: The Impact of Ball Milling Anatase Nanopowders with TiH2.

Xuemei Zhou1, Ning Liu1, Jochen Schmidt2, Axel Kahnt3, Andres Osvet4, Stefan Romeis2, Eva M Zolnhofer5, Venkata Ramana Reddy Marthala6, Dirk M Guldi3, Wolfgang Peukert2, Martin Hartmann6, Karsten Meyer5, Patrik Schmuki1.   

Abstract

Ball milling TiO2 anatase together with TiH2 can create an effective photocatalyst. The process changes the lattice and electronic structure of anatase. Lattice deformation created by mechanical impact combined with hydride incorporation yield electronic gap-states close to the conduction band of anatase. These provide longer lifetimes of photogenerated charge carriers and lead to an intrinsic cocatalytic activation of anatase for H2 evolution.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  anatase; ball milling; hydrogen evolution; photocatalysis; titanium hydride

Year:  2016        PMID: 27886413     DOI: 10.1002/adma.201604747

Source DB:  PubMed          Journal:  Adv Mater        ISSN: 0935-9648            Impact factor:   30.849


  3 in total

1.  Fabrication of a porous NiFeP/Ni electrode for highly efficient hydrazine oxidation boosted H2 evolution.

Authors:  Honglei Wang; Shengyang Tao
Journal:  Nanoscale Adv       Date:  2021-03-02

2.  Mechano-synthesized orange TiO2 shows significant photocatalysis under visible light.

Authors:  Ken-Ichi Saitow; Yufeng Wang; Shintaro Takahashi
Journal:  Sci Rep       Date:  2018-10-19       Impact factor: 4.379

Review 3.  Photocatalysis with Reduced TiO2: From Black TiO2 to Cocatalyst-Free Hydrogen Production.

Authors:  Alberto Naldoni; Marco Altomare; Giorgio Zoppellaro; Ning Liu; Štěpán Kment; Radek Zbořil; Patrik Schmuki
Journal:  ACS Catal       Date:  2018-11-30       Impact factor: 13.084

  3 in total

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