Literature DB >> 27886287

A carborane-incorporated mononuclear Co(ii) complex showing zero-field slow magnetic relaxation.

Deshuang Tu1, Dong Shao1, Hong Yan1, Changsheng Lu1.   

Abstract

An air-stable mononuclear Co(ii) complex bearing an o-carborane dithiolate ligand has been synthesized which shows slow relaxation of magnetization in the absence of an applied field and a hysteresis loop at 1.8 K. This is the first example of a carborane-incorporated complex that displays SMM properties.

Entities:  

Year:  2016        PMID: 27886287     DOI: 10.1039/c6cc07728e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Synthesis of 9-borafluorene analogues featuring a three-dimensional 1,1'-bis(o-carborane) backbone.

Authors:  Sam Yruegas; Jonathan C Axtell; Kent O Kirlikovali; Alexander M Spokoyny; Caleb D Martin
Journal:  Chem Commun (Camb)       Date:  2019-03-05       Impact factor: 6.222

2.  Trigonally Distorted Hexacoordinate Co(II) Single-Ion Magnets.

Authors:  Ivan Nemec; Ondřej F Fellner; Berenika Indruchová; Radovan Herchel
Journal:  Materials (Basel)       Date:  2022-01-29       Impact factor: 3.623

3.  Strong Exchange Couplings Drastically Slow Down Magnetization Relaxation in an Air-Stable Cobalt(II)-Radical Single-Molecule Magnet (SMM).

Authors:  Uta Albold; Heiko Bamberger; Philipp P Hallmen; Joris van Slageren; Biprajit Sarkar
Journal:  Angew Chem Int Ed Engl       Date:  2019-06-06       Impact factor: 15.336

  3 in total

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