| Literature DB >> 27886103 |
Ching-Ping Liang1, Cheng-Shin Jang2, Cheng-Wei Liang3, Jui-Sheng Chen4.
Abstract
In the Pingtung Plain of southern Taiwan, elevated levels of NO₃--N in groundwater have been reported. Therefore, efforts for assessing groundwater vulnerability are required as part of the critical steps to prevent and control groundwater pollution. This study makes a groundwater vulnerability assessment for the Pingtung Plain using an improved overlay and index-based DRASTIC model. The improvement of the DRASTIC model is achieved by reassigning the weighting coefficients of the factors in this model with the help of a discriminant analysis statistical method. The analytical results obtained from the improved DRASTIC model provide a reliable prediction for use in groundwater vulnerability assessment to nitrate pollution and can correctly identify the groundwater protection zones in the Pingtung Plain. Moreover, the results of the sensitivity analysis conducted for the seven parameters in the improved DRASTIC model demonstrate that the aquifer media (A) is the most sensitive factor when the nitrate-N concentration is below 2.5 mg/L. For the cases where the nitrate-N concentration is above 2.5 mg/L, the aquifer media (A) and net recharge (R) are the two most important factors.Entities:
Keywords: DRASTIC model; NO3−-N; discriminant analysis; groundwater; vulnerability
Mesh:
Year: 2016 PMID: 27886103 PMCID: PMC5129377 DOI: 10.3390/ijerph13111167
Source DB: PubMed Journal: Int J Environ Res Public Health ISSN: 1660-4601 Impact factor: 3.390
Figure 1Spatial distribution of nitrate concentrations. The triangles size represents nitrate concentrations of <1, 1–3, 3–6, 6–10, and >10.0 mg/L, respectively.
Figure 2Study area and land use.
Figure 3Hydrogeological profile.
The recharge ratios for different land use types. (Modified from Chow et al. [21]). The recahge ratio is calculated based on the runoff data for different land use types provided by Chow et al. [21].
| Land Use Types | Recharge Ratio |
|---|---|
| Developed area | |
| Road/building roof | 0.10 |
| Park/lawn | 0.55 |
| Undeveloped | |
| Cultivated land | 0.60 |
| Pasture/range | 0.65 |
| Forest/woodlands | 0.70 |
Weights, ranges, and ratings for the seven parameters in the DRASTIC model.
| D(m) a | R(cm) a | A b | S b | T a | I b | C(Cmd/m2) a | |
|---|---|---|---|---|---|---|---|
| 5 | 4 | 3 | 2 | 1 | 5 | 3 | |
| 0–1.5 | - | vcG, cG, mG, fG | vcG, cG, mG, fG | 0–2 | vcG, cG, mG, fG | 81> | |
| 1.6–4.5 | >26 | vcS | vcS | 3–6 | vcS | - | |
| - | 18–25 | - | - | - | - | 41–80 | |
| 4.6–9.0 | - | cS | cS | - | cS | - | |
| - | 11–17 | - | - | - | - | 29–40 | |
| 9.1–15 | - | mS | mS | 7–12 | mS | - | |
| - | - | fS | fS | - | fS | 13–28 | |
| 16–22.5 | 6~10 | vfS | vfS | 13–18 | vfS | - | |
| 22.6–30 | - | Z | Z | - | Z | 4–12 | |
| 31+ | 0–5 | M, C | M, C | 19+ | M, C | <4 |
a the ratings proposed by Aller et al. [7]; b cG: coarse gravel; G: gravel; fG: fine gravel; cS: coarse sand; mS: medium sand; fS: fine sand; M: mud; C: clay.
Figure 4Box plots showing the distribution of groundwater nitrate concentration for the statistically different classes for the seven parameters in the DRASTIC model. (a) Depth to water; (b) net recharge; (c) aquifer media; (d) soil media; (e) topography; (f) impact of vadose zone; (g) hydraulic conductivity. after the DRASTIC model.
Figure 5Spatial distribution of the ratings for the seven factors of the DRASTIC model in the Pingtung Plain. D: Depth to water; R: net Recharge; A: Aquifer media; S: Soil media; T: Topography; I: Impact of vadose zone; C: hydraulic Conductivity.
Figure 6Comparison of the spatial distribution of (a) DRASTIC vulnerability index and (b) nitrate concentrations.
Summary of results obtained by the discriminant analysis.
| Thresholds (mg/L) | Total Correct Classification Ratios (%) | Correct Classification Ratios of Polluted Groups (%) | Correct Classification Ratios of Unpolluted Groups (%) | AUC |
|---|---|---|---|---|
| Intrinsic DRASTIC model | ||||
| 2.5 | 64 | 62 | 66 | 0.71 |
| 5.5 | 60 | 62 | 60 | 0.63 |
| 7.5 | 64 | 86 | 61 | 0.76 |
| Modified DRASTIC model | ||||
| 2.5 | 74 | 63 | 83 | 0.84 |
| 5.5 | 75 | 69 | 78 | 0.80 |
| 7.5 | 79 | 86 | 78 | 0.84 |
AUC: area under the curve.
Figure 7Spatial distribution of the vulnerability index obtained from the modified DRASTIC model for three distinct thresholds: (a) 2.5; (b) 5.5; and (c) 7.5 mg/L.
Absolute difference for each factor between the polluted and unpolluted groups for the three distinct nitrate-N thresholds of 2.5, 5.5, and 7.5 mg/L.
| −0.98 | 0.08 | 2.51 | −0.59 | 1.29 | 0.78 | 1.39 | |
| −1.31 | 0.08 | 1.09 | −0.51 | 1.26 | 0.43 | 1.26 | |
| 0.331 | 0.002 | 1.426 | 0.082 | 0.030 | 0.348 | 0.130 | |
| 0.07 | 2.66 | 1.22 | −1.49 | 4.18 | 0.88 | 1.15 | |
| 0.07 | 1.84 | 0.76 | −1.60 | 4.06 | 0.56 | 1.10 | |
| 0.006 | 0.820 | 0.464 | 0.107 | 0.121 | 0.318 | 0.043 | |
| 0.50 | 2.54 | 2.32 | −0.97 | 3.58 | 0.95 | −2.95 | |
| 0.58 | 1.77 | 1.32 | −0.91 | 3.48 | 0.55 | −2.87 | |
| 0.082 | 0.764 | 0.997 | 0.065 | 0.094 | 0.404 | 0.080 |
D: Depth to water; R: net Recharge; A: Aquifer media; S: Soil media; T: Topography; I: Impact of vadose zone; C: hydraulic Conductivity.