Literature DB >> 27878520

A Coumarin-Based Luminescent Chemosensor for Recognition of Cu2+ and its In-Situ Complex for CN- Sensing via Cu2+ Displacement Approach.

Soma Mukherjee1, Shrabani Talukder2.   

Abstract

A new coumarin based chemosensor has been developed for selective fluorescent recognition of Cu2+ in MeOH/H2O (4:1, v/v at pH = 7.2 aqueous solution) medium with 1:1 binding stoichiometry. The in-situ prepared Cu2+ complex displays high selectivity towards CN- via Cu2+ displacement approach with detection limit in the micro molar range. Moreover, in presence of Cu2+, the receptor exhibits reversible emission change with EDTA and thus offers an interesting property of molecular 'IMPLICATION' logic gate with Cu2+ and EDTA as chemical inputs.

Entities:  

Keywords:  CN−; Chemosensor; Coumarin; Cu2+; Logic gate

Year:  2016        PMID: 27878520     DOI: 10.1007/s10895-016-1974-1

Source DB:  PubMed          Journal:  J Fluoresc        ISSN: 1053-0509            Impact factor:   2.217


  18 in total

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Review 4.  Essentiality of copper in humans.

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9.  Colorimetric cyanide detection using an azobenzene acid in aqueous solutions.

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10.  Coumarin-derived Cu(2+)-selective fluorescence sensor: synthesis, mechanisms, and applications in living cells.

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  1 in total

1.  A New Fluorescent "Turn-Off" Coumarin-Based Chemosensor: Synthesis, Structure and Cu-Selective Fluorescent Sensing in Water Samples.

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