Development of a simple method for fabrication of transparent conductive films with high mechanical strength.

We have developed a simple method of fabricating transparent conductive films with a high mechanical strength on glass and indium tin oxide substrates. It does not require a large excess of organic solvents and polymerization catalysts and can yield smooth films by spin-coating of a mixture of a commercially available aqueous dispersion of poly(3,4-ethylenedioxythiophene)-poly(4-styrene sulfonate) and a neat liquid of tetraethyl orthosilicate. Preparation conditions such as feed ratio, kinds of additives, and annealing temperature and time were optimized to give highly conductive, transparent and mechanically strong films.