Literature DB >> 27873438

Polysulfates [Sn O3n+1 ]2- : With the [S6 O19 ]2- Anion, has the End been Reached?

Lisa Verena Schindler1, Anna Becker1, Maria Wieckhusen2, Thorsten Klüner2, Mathias S Wickleder1.   

Abstract

The S6 O192- ion was obtained both as rubidium and ammonium salt from the reaction of the respective sulfate with SO3 . It is the largest polysulfate ion known to date and exhibits a chain of six vertex-connected [SO4 ] tetrahedra. The unique compound was comprehensively characterized and the bonding within the anion was elucidated by theoretical investigations.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  polysulfates; solid-state chemistry; structural chemistry

Year:  2016        PMID: 27873438     DOI: 10.1002/anie.201607629

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  S6 N2 O15 -A Nitrogen-Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido-tris-Sulfuric Acid.

Authors:  David van Gerven; Mathias S Wickleder
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-04       Impact factor: 15.336

  1 in total

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