Literature DB >> 27862399

Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups.

Sergey Z Vatsadze1, Yulia D Loginova1, Gabriel Dos Passos Gomes2, Igor V Alabugin2.   

Abstract

Stereoelectronic factors account for the apparent reversal of donor-acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  acceptors; donors; functional groups; reactive intermediates; stereoelectronic effects

Year:  2016        PMID： 27862399     DOI： 10.1002/chem.201603491

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  7 in total

1.  Cobalt-Catalyzed C(sp2)-C(sp3) Suzuki-Miyaura Cross-Coupling Enabled by Well-Defined Precatalysts with L,X-Type Ligands.

Authors:  L Reginald Mills; David Gygi; Jacob R Ludwig; Eric M Simmons; Steven R Wisniewski; Junho Kim; Paul J Chirik
Journal:  ACS Catal       Date:  2022-01-20       Impact factor: 13.700

2.  Reactions of the Lipid Hydroperoxides With Aminic Antioxidants: The Influence of Stereoelectronic and Resonance Effects on Hydrogen Atom Transfer.

Authors:  Yu-Zhen Li; Xiao-Lu Zhou; Bao-Qi Huo; De-Zhan Chen; Zhao-Hua Liu; Xie-Huang Sheng
Journal:  Front Chem       Date:  2019-12-17       Impact factor: 5.221

3.  Synthesis of new pyridines with sulfonamide moiety via a cooperative vinylogous anomeric-based oxidation mechanism in the presence of a novel quinoline-based dendrimer-like ionic liquid.

Authors:  Morteza Torabi; Meysam Yarie; Mohammad Ali Zolfigol; Shamila Rouhani; Shohreh Azizi; Temitope O Olomola; Malik Maaza; Titus A M Msagati
Journal:  RSC Adv       Date:  2021-01-22       Impact factor: 3.361

4.  Catalytic application of sulfamic acid-functionalized magnetic Fe3O4 nanoparticles (SA-MNPs) for protection of aromatic carbonyl compounds and alcohols: experimental and theoretical studies.

Authors:  Sepideh Khaef; Mohammad Ali Zolfigol; Avat Arman Taherpour; Meysam Yarie
Journal:  RSC Adv       Date:  2020-12-21       Impact factor: 4.036

5.  Testing the limits of radical-anionic CH-amination: a 10-million-fold decrease in basicity opens a new path to hydroxyisoindolines via a mixed C-N/C-O-forming cascade.

Authors:  Quintin Elliott; Gabriel Dos Passos Gomes; Christopher J Evoniuk; Igor V Alabugin
Journal:  Chem Sci       Date:  2020-02-21       Impact factor: 9.825

6.  Organocatalyzed synthesis of fluorinated poly(aryl thioethers).

Authors:  Nathaniel H Park; Gabriel Dos Passos Gomes; Mareva Fevre; Gavin O Jones; Igor V Alabugin; James L Hedrick
Journal:  Nat Commun       Date:  2017-08-01       Impact factor: 14.919

7.  Bispidine Platform as a Tool for Studying Amide Configuration Stability.

Authors:  Dmitry P Krut'ko; Alexey V Medved'ko; Konstantin A Lyssenko; Andrei V Churakov; Alexander I Dalinger; Mikhail A Kalinin; Alexey O Gudovannyy; Konstantin Y Ponomarev; Eugeny V Suslov; Sergey Z Vatsadze
Journal:  Molecules       Date:  2022-01-10       Impact factor: 4.411
  7 in total

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