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Literature DB >> 27860056

Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.

Merle Arrowsmith¹, Holger Braunschweig¹, Tom E Stennett¹.

Abstract

Recent years have seen rapid advances in the chemistry of small molecules containing electron-precise boron-boron bonds. This Review provides an overview of the latest methods for the controlled synthesis of B-B single and multiple bonds as well as the ever-expanding range of reactivity displayed by B-B multiple bonds.

Entities: Chemical

Keywords: boron; main-group chemistry; multiple bonding; organoboron chemistry; transition metals

Year: 2016 PMID： 27860056 DOI： 10.1002/anie.201610072

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

16 in total

1. Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B-C bond cleavage.

Authors: Alexander Okorn; Arumugam Jayaraman; Lukas Englert; Merle Arrowsmith; Theresa Swoboda; Jeanette Weigelt; Carina Brunecker; Merlin Hess; Anna Lamprecht; Carsten Lenczyk; Maximilian Rang; Holger Braunschweig
Journal: Chem Sci Date: 2022-06-14 Impact factor: 9.969

2. Selective Benzylic CH-Borylations by Tandem Cobalt Catalysis.

Authors: Pradip Ghosh; Roland Schoch; Matthias Bauer; Axel Jacobi von Wangelin
Journal: Angew Chem Int Ed Engl Date: 2021-11-22 Impact factor: 16.823

3. An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry.

Authors: Wei Lu; Arumugam Jayaraman; Felipe Fantuzzi; Rian D Dewhurst; Marcel Härterich; Maximilian Dietz; Stephan Hagspiel; Ivo Krummenacher; Kai Hammond; Jingjing Cui; Holger Braunschweig
Journal: Angew Chem Int Ed Engl Date: 2021-12-03 Impact factor: 16.823

4. Isolation of diborenes and their 90°-twisted diradical congeners.

Authors: Julian Böhnke; Theresa Dellermann; Mehmet Ali Celik; Ivo Krummenacher; Rian D Dewhurst; Serhiy Demeshko; William C Ewing; Kai Hammond; Merlin Heß; Eckhard Bill; Eileen Welz; Merle I S Röhr; Roland Mitrić; Bernd Engels; Franc Meyer; Holger Braunschweig
Journal: Nat Commun Date: 2018-03-22 Impact factor: 14.919

Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.

1. Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B-C bond cleavage.

2. Selective Benzylic CH-Borylations by Tandem Cobalt Catalysis.

3. An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry.

4. Isolation of diborenes and their 90°-twisted diradical congeners.

5. Mild synthesis of diboryldiborenes by diboration of B-B triple bonds.

6. Hexahalodiborate Dianions: A New Family of Binary Boron Halides.

7. Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes.

8. Magnesium Boryl Reactivity with 9-BBN and Ph₃ B: Rational B-B' Bond Formation and Diborane Isomerization.

9. Striking transformations of the hydroborylene ligand in a HB:→Ni^II complex with isocyanides and CO.

Review 10. Boron: Its Role in Energy-Related Processes and Applications.